11-07

M.J.J. Coenen, M. Cremers, D. den Boer, F.J. van den Bruele, T. Khoury, M. Sintic,

M.J. Crossley, W.J.P. van Enckevort, B.L.M. Hendriksen, J.A.A.W. Elemans, S. Speller,

Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers,

Che. Commun. 47 (2011) 9666-9668

Abstract

The transition from low to high density 2D surface structures of copper porphyrins at a liquid/solid interface requires specific defects at which nearly all exchange of physisorbed molecules with those dissolved in the supernatant occurs.