Three different ways are used to etch diamond {001} and {111} faces
by oxidative methods: gas phase etching in dry oxygen, gas phase etching
in a mixture of oxygen and water vapour, and liquid etching in molten potassium
nitrate. The surface topography of the etched surfaces is compared with
the theoretically predicted morphology. It appears that in most cases the
experimental results are in contradiction to theory. These discrepancies
are explained by the reactions between the diamond surfaces and the adsorbed
oxygen, which are able either to stabilise or to destabilise the surfaces.
Of these three methods, etching in molten potassium nitrate was found to
be the best for revealing dislocations. (C) 2000 Elsevier Science S.A.
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