Abstract:
The morphology of beta-2 n.n.n triacylglycerol crystals is predicted
using a revised interpretation of the Hartman-Perdok theory. This modification
takes into account the step free energy and therefore the growth conditions
and therefore leads to a better understanding of the observed morphology.
For long chain molecules, the three-dimensional morphology is also reflected
in the anisotropic step patterns on the basal crystal plane. The patterns
observed on these faces using Atomic Force Microscopy can also be understood
from this revised interpretation of the Hartman-Perdok theory.