In situ optical and birefringence measurements
were applied in observing the crystallisation of very thin (greater than
or equal to 1.1 mu m) n-paraffin crystals. Next, homologue impurities were
found to reduce the crystal thickness even further to approximately 0.4
mu m. As such thin crystals are very sensitive to adsorption of (sub-)
micron particles (e.g. dust particles) a new type of growth, i.e. ''particle-induced
rough growth'', is induced. This growth is akin to the growth of steps
in the presence of immobile impurities adsorbed on the surface. The measured
mean distance between the obstructing (sub-) micron particles (12 mu m)
is used to calculate the surface energy (36 mJ/m(2)) of the top and bottom
faces of the n-paraffin crystals. And it was shown that this is a reasonable
value for the surface energy of {001} faces of n-paraffin crystals. Further,
it was shown that at fixed concentrations the saturation temperatures for
thin crystals are different from those for thick crystals. These results
can be explained in terms of a Gibbs-Thomson effect.